𝔖 Bobbio Scriptorium
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Electronic quenching of the B 2Σ+ state of AlO

✍ Scribed by Mark L. Campbell; Roy E. McClean; Nancy L. Garland; H.H. Nelson

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
201 KB
Volume
194
Category
Article
ISSN
0009-2614

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✦ Synopsis

Electronic quenching rate constants for the B 2E+ state of AIO were determined using a pulsed-laser photolysis laser-induced fluorescence technique by examining fluorescence decay rates in the presence of seven atomic and molecular collision partners. The two polar molecules CO and NO were found to have rate constant s of 4.8 X 10-12 and 1.8 × 10-to cm 3 s-t, respectively. The nonpolar gases He, H2, N2, CO2 and Xe were found to be poor quenchers with a bimolecular quenching rate constant having an upper bound of 1 × 10-13 cm 3 s-z for He, H2, N2 and Xe and 1 × 10 -12 cm 3 for COz.

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