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Chemiluminescence and reactivity of aluminum monoxide (AlO) in the excited B(2Σ+) state

✍ Scribed by B. Bescós; G. Morley; A. González Ureña

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
403 KB
Volume
244
Category
Article
ISSN
0009-2614

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✦ Synopsis

Using laser ablation of aluminum samples under moderate 0 2 pressures the chemiluminescence and reactivity of the excited AIO(B(2E +)) state have been measured. The analysis of the AIO(B) fluorescence corresponding to emission from different internal states with various oxygen concentrations has allowed us to obtain rate constants values for the AIO(B)+O 2 reaction for different vibrational states. The results are k(v=o)= !.1 x 10 -l~ molecule -~ cm 3 s -I and k(,.=L)= 1.1 X 10 -~l molecule -1 cm 3 s -1.

📜 SIMILAR VOLUMES

Electronic transition moment of the AlO(
Electronic transition moment of the AlO(B 2Σ+−X 2Σ+) emission. Analysis of the R dependence of the Al2+O2− character in the X 2Σ+ state
✍ Noriko Sato; Haruhiko Ito; Kozo Kuchitsu 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 440 KB

The dependence of the electronic transition moment, Re(R), of the A10(B 2X+-X 2E+) system on the internuclear distance, R, has been determined by an analysis of the intensity distribution of the emission spectra as Re(R)= [1 -2.29(13XR/,~-1.5) 2] (1.510 A ~<R ~< 1.836 ,~). The R dependences of Re(R)

Electronic transition moment of the AlO(
Electronic transition moment of the AlO(B2Σ+−X2Σ+) emission. Analysis of the R dependence of the Al2+O2− character in the X2Σ+ state (Chem. Phys. Letters 240 (1995) 10)
✍ N. Sato; H. Ito; K. Kuchitsu 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 43 KB

The Publisher sincerely regrets the following errors which have been made in the above-mentioned paper. On page 13, in the sentence above Eq. ( 8), "0 and 1.5 A" should read "0 k1 and 1.5 A". On page 14, Eq. ( 11) should read On page 14, in the last sentence of the right-hand column ul" should read