## Abstract Electroabsorption (Stark effect) measurements on the intervalence charge‐transfer (IVCT) transitions in the diastereoisomers of [{Ru(bpy)~2~}~2~(μ‐bpt^–^)]^4+^ [bpy = 2,2′‐bipyridine, bpt^–^ = 3,5‐bis(2‐pyridyl)‐1,2,4‐triazolate] in __n__‐butyronitrile glass at 77 K reveal effective cha
Electronic energy transfer in bimetallic Ru-Os complexes containing the 3,5-bis(pyridin-2-yl)-1,2,4-triazolate bridging ligand
✍ Scribed by Luisa De Cola; Francesco Barigelletti; Vincenzo Balzani; Ronald Hage; Jaap G. Haasnoot; Jan Reedijk; Johannes G. Vos
- Book ID
- 107735104
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 486 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Reactions of [RhClL] (L,=diolefin or (CO)(PPh,)) with the deprotonated form of the ligand 3,5bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh&)(bpt)]. Cationic, mono-and dinuclear species of formulae [Rh&.)(Hbpt)]+, [{Rhb}\*(bpt)]+ and [{Rh&.}@bpt)]\*+, where b=diolefi
## Abstract 2,6‐Bis(5‐thioxo‐4,5‐dihydro‐1,2,4‐triazole‐3‐yl)pyridines (**3**, **4**) were used for the first time as ligand in ruthenium catalyzed transfer hydrogenation of acetophenone. The __in situ__ prepared three‐component system Ru(II)/tridentate triamine ligands (**3a**–**3d**, **4a**–**4d*