Electronic and solvent effects on the bonding mode of the selenocyanate ion in trans-selenocyanatobis(dimethylglyoximato)(substituted pyridine)cobalt(III) complexes
✍ Scribed by J.L. Allison; J.L. Burmeister
- Book ID
- 114041074
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 576 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0020-1693
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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy
## Abstract The kinetics of solvolysis of __trans__‐dichlorobis(__N__‐methylethylenediamine)cobalt(III) complex have been investigated in aqua‐organic solvent media (0–60% (v/v) cosolvent) at 25 ≤ t°C ≤ 60, using __n__‐propanol and __tert__‐butyl alcohol as cosolvents. The first‐order rate constant