Electronic absorption band assignments for copper(II) salicylaldimine complexes
β Scribed by T.N. Waters; P.E. Wright
- Book ID
- 118908550
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 248 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-1902
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π SIMILAR VOLUMES
Copper(II) mononuclear complexes with the polyazamacrocyclic ligands NOTA (1,4,7-triazacyclononane-N,N',N''triacetate), DOTA (1,4,7,10-tetraazacyclo-dodecane-N,N',N'',N'''-tetraacetate), NOTP [1,4,7-triazacyclononane-N,N',N''-tris(methylenephosphonate)] and DOTP [1,4,7,10tetraazacyclododecane-N,N',N
A Monte Carlo method has been used to analyze the absorption band shape for A-+E electronic transitions, with Jahn-Teller and pseudo-Jahn-Teller interactions included in the Hamiltonian. The results obtained suggest a reconsideration of the assignment of d-d transitions in trigonal bipyramidal coppe
The electronic spectra (d-d transitions) of the following pseudotetrahedral complexes, Cu(L-L)22+, L-L = 2,2'-dipyridylamine (HDPA); 3,3'-dimethyl-2,2'-dipyridylamine (HMPA); 2-pyridyl-2'-pyrimidylamine (HPPA); 2-pyridyl-2'-thiazolylamine (HPTA) were interpreted by the Angular Overlap Model (AOM) in