Absorption band shape in five-coordinated copper(ii) complexes: influence of the Jahn-Teller effect

✍ Scribed by M. Bacci

• Publisher: Elsevier Science
• Year: 1987
• Tongue: English
• Weight: 233 KB
• Volume: 134
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(87)87110-5

✦ Synopsis

A Monte Carlo method has been used to analyze the absorption band shape for A-+E electronic transitions, with Jahn-Teller and pseudo-Jahn-Teller interactions included in the Hamiltonian. The results obtained suggest a reconsideration of the assignment of d-d transitions in trigonal bipyramidal copper( II) complexes may be in order.