Electron transfer processes in the photolysis of ferrocene in solution
β Scribed by J.A. Powell; S.R. Logan
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 614 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0047-2670
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Some recent studies of inner-sphere and outer-sphere electron-transfer reactions in solution are described. Various indirect criteria for determining the mechanisms of electron-transfer re actions and the question of ligand bridging at electrodes are discussed.
The electrochemical behavior of ferrocene in an aqueous microemulsion (pentan-1-al/sodium dodecyl sulfate (SDS)/aq. H,SO,) has been studied using an ultramicroelectrode. Contrary to the generally expected reversible peak, the experiments show the presence of a second oxidation peak during the revers