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Electron transfer processes. 19. Reaction of aryl radicals with anions in aqueous solution

โœ Scribed by Russell, Glen A.; Metcalfe, A. R.


Book ID
127062315
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
444 KB
Volume
101
Category
Article
ISSN
0002-7863

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โœ Gernot Boche; Dieter R. Schneider ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals