๐”– Bobbio Scriptorium
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Reactions of resonance stabilized anions. XXX. Electron-transfer processes. 8. Coupling reactions of radicals with carbanions

โœ Scribed by Russell, Glen A.; Danen, Wayne C.


Book ID
120569525
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
811 KB
Volume
90
Category
Article
ISSN
0002-7863

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Configurational stability of cyclopropyl
โœ Gernot Boche; Dieter R. Schneider ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals