Electron transfer in molecules with conformational transitions

✍ Scribed by D.V. Matyushov

• Book ID: 103030999
• Publisher: Elsevier Science
• Year: 1993
• Tongue: English
• Weight: 464 KB
• Volume: 203
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(93)85376-y

✦ Synopsis

Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains, besides the activation enthalpy, a temperaturedependent entropic term AS= a, +a,T.