Rates of conformational transitions in branched chain molecules
โ Scribed by Skolnick, Jeffrey; Mattice, Wayne L.
- Book ID
- 126184200
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 990 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The conformational transitions lead to reorientations of a small fraction only of a chain molecule. This follows from the analysis of the barrier crossing problem according to the Framers theory. Therefore, the librational motion operating after a transition is responsible for the attainment of the
Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains, besides the activation enthalpy, a temperaturedependent entropic term AS= a, +a,T.