Electron transfer in molecules with conf
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D.V. Matyushov
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Article
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1993
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Elsevier Science
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English
β 464 KB
Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains, besides the activation enthalpy, a temperaturedependent entropic term AS= a, +a,T.