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Electron spin resonance quantitative monitoring of five different radicals in γ-irradiated polyvinylidene fluoride

✍ Scribed by Dumas, Ludovic; Albela, Belén; Bonneviot, Laurent; Portinha, Daniel; Fleury, Etienne

Book ID
122713531
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
559 KB
Volume
86
Category
Article
ISSN
0969-806X

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The primary neutral radicals in y-irradiated liquid methanol at 194°K have been spin trapped with phenyl-t-butyl nitrone. The principal primary radicals are CH20H and CH30. In contrast to earlier work, these radicals are formed with an initial ratio of CHzCH/CHaO J 1.5 which agrees with gas phase ma