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Electron spin resonance of trapped free radicals and the photoinduced radical conversion in γ-irradiated isotactic polypropylene

✍ Scribed by Iwasaki, Machio ;Ichikawa, Takahisa ;Toriyama, Kazumi

Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
224 KB
Volume
5
Category
Article
ISSN
0449-2986

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✍ S.W. Mao; Larry Kevan 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 295 KB

The primary neutral radicals in y-irradiated liquid methanol at 194°K have been spin trapped with phenyl-t-butyl nitrone. The principal primary radicals are CH20H and CH30. In contrast to earlier work, these radicals are formed with an initial ratio of CHzCH/CHaO J 1.5 which agrees with gas phase ma