956, (1 11 3) Capital Federal, Argentina The electron impact mass spectral fragmentation of a series of 3-substituted-1,2,3,4-tetrahydroisoquinolinc~ are reported. The principal fragmentation modes of these compounds comply with the main generalizations reacbed earlier with simpler systems. Complet
Electron impact ionization mass spectra of some substituted dipyrido[1,2-a:4,3-d]pyrimidinones
✍ Scribed by Esa Mäki; Kalevi Pihlaja; Imre Huber; Ferenc Fülöp; Gábor Bernáth; Pirjo Vainiotalo
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 349 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
The electron impact ionization mass spectra of dipyrido [1,2‐a:4,3‐d]pyrimidinones are strongly influenced by the degree of aromaticity of the fused rings. The molecular ions of the compounds are fairly stable. The main routes of fragmentation involve formation of the [M – H]^+^ ion and loss of substituents, H~2~CN˙, CO and alkyl radicals.
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The positive electron impact (EI) and isobutane chemical ionization (CI) mass spectra of six nitramine nitrates were studied with the aid of some accurate mass measurements. In the EI spectra, fl fission relative to both the nitramine and nitrate ester is important. In the C1 spectra a major ion occ