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Electron impact mass spectrometry of some 3-substituted 1,2,3,4-tetrahydroisoquinolines

✍ Scribed by Adriana F. Ibañez; Graciela Y. Moltrasio Iglesias

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 159 KB
Volume: 26
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210260303

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✦ Synopsis

956, (1 11 3) Capital Federal, Argentina

The electron impact mass spectral fragmentation of a series of 3-substituted-1,2,3,4-tetrahydroisoquinolinc~ are reported. The principal fragmentation modes of these compounds comply with the main generalizations reacbed earlier with simpler systems. Complete aromatizations to form the isoquinolinium ion are observed only for compounds 5 and 7 and no retro-Diels-Alder cleavage is observed when R' is a benzyl goup.

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