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Chemical ionization and electron impact mass spectra of alicyclic substituted 2-aryl-1,3-dithianes

โœ Scribed by Charles J. Shaw; Vinayak V. Kane


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
245 KB
Volume
15
Category
Article
ISSN
1076-5174

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## Abstract The mass spectra of 20 1,3โ€dithianes were studied. The fragmentation patterns including the loss of 74 u and 107 u and clearage of the substituent at Cโ€2 depended strongly on the nature of the substituents at that position. 2,2โ€Diphenylโ€1,3โ€dithiane undergoes an atypical fragmentation i

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Table 1. The EI mass spectra, showing peaks of >5% relative abundance (RA), of compounds 1-10, using 70 eV electrons Compound m/z (% RA) 1 315(M, 55) 314(10) 161(10) 160(89) 159(13) 107(12) 106(100) 105(11) 104(9) 91(33) 77(22) 65(15) a 2 345(M, 4) 316(7) 315(19) 314(100) 190(11) 175(7) 172(5) 160(1