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Mass spectra of 1,3-dithiaspiranes and 2-aryl-1,3-dithianes

✍ Scribed by Gong-Yih Shiue; Shaw-Tao Lin; Yueh-Hsiung Kuo; Zong-Shiow Chen

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 365 KB
Volume: 30
Category: Article
ISSN: 1076-5174
DOI: 10.1002/jms.1190300310

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The mass spectra of 20 1,3‐dithianes were studied. The fragmentation patterns including the loss of 74 u and 107 u and clearage of the substituent at C‐2 depended strongly on the nature of the substituents at that position. 2,2‐Diphenyl‐1,3‐dithiane undergoes an atypical fragmentation in which two hydrogens migrate from the phenyl ring, with the formation of a fluorene skeleton.

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