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Electron impact and fast atom bombardment mass spectrometry in the characterization of some new macrocycles containing a 1,3,5-triazine moiety

✍ Scribed by L. Corda; M. P. Bullitta; E. Maccioni; G. Podda; D. Favretto; P. Traldi

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
298 KB
Volume
27
Category
Article
ISSN
1076-5174

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✦ Synopsis

The mass spectrometric behaviour of four new macrocyclic compounds, all containing the 13,Striazine moiety, was studied with the aid of different ionization methods and mass-analysed ion kinetic energy spectrometry. Extensive fragmentation of the oligoethylene glycol side-chains is observed, with the usual loss of C2H,0 units. The favoured cleavage of the ethereal bond nearest to the etherocyclic ring gives rise-to both complementary ions.

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