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Electrode processes of the V(III)/V(II) and Eu(III)/Eu(II) systems in mixed water + acetone solvents

✍ Scribed by Libuše Kišová; Libor Reichstädter; Jaro Komenda


Publisher
Elsevier Science
Year
1987
Weight
628 KB
Volume
230
Category
Article
ISSN
0022-0728

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Spectrophotometric and electrochemical behaviour of V(III) ions was investigated in H,O + DMPU and H,O + HMPA mixed solvents. While optical studies have revealed the resolvation of V(III) already in Hz0 rich solutions, it has been found that the reduction of V(II1) to V(H) at the mercury electrode y