Kinetics and mechanism of the reaction o
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Anatoly M. Egorov; Svetlana A. Matyukhova; Alexander V. Anisimov
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Article
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2005
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John Wiley and Sons
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English
⚖ 182 KB
👁 1 views
The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k • ) vs the substituent constant σ gave good correlations (ρ = 0.24, S ρ = 0.03, r = 0.