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Kinetics and mechanism of the V(III) + e− ⇌ V(II) reaction at a mercury electrode in water + dimethylformamide mixtures

✍ Scribed by Waldemar Górski; Zb́igniew Galus


Publisher
Elsevier Science
Year
1986
Weight
968 KB
Volume
201
Category
Article
ISSN
0022-0728

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The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k • ) vs the substituent constant σ gave good correlations (ρ = 0.24, S ρ = 0.03, r = 0.