Electrochemistry of Heteroleptic Tris(phthalocyaninato) Rare Earth(III) Complexes
✍ Scribed by Peihua Zhu; Na Pan; Changqin Ma; Xuan Sun; Dennis P. Arnold; Jianzhuang Jiang
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 134 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The electrochemistry of homoleptic substituted phthalocyaninato rare earth double‐decker complexes M(TBPc)~2~ and M(OOPc)~2~ [M = Y, La...Lu except Pm; H~2~TBPc = 3(4),12(13),21(22),30(31)‐tetra‐__tert__‐butylphthalocyanine, H~2~OOPc = 3,4,12,13,21,22,30,31‐octakis(octyloxy)phthalocyani
A series of eleven heteroleptic bis(phthalocyaninato) rare earth double-deckers [M III (pc){pc(a-OC 5 H 11 ) 4 }] 1 ± 11 (M Y, SmÀLu; pc phthalocyaninato; pc(a-OC 5 H 11 ) 4 1,8,15,22-tetrakis(1-ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [M III (pc)(acac)]-induced (acac acet