Anion-Induced Assembly of Hexacoordinate Rare-Earth(III) Complexes
✍ Scribed by Stefania Tanase; Silvia Sottini; Valerie Marvaud; Edgar J. J. Groenen; Lise-Marie Chamoreau
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 308 KB
- Volume
- 2010
- Category
- Article
- ISSN
- 1434-1948
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Novel molecular metal salts comprising an organic donor 2,5-bis(1, 3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene (BDT-TTP) and lanthanide nitrato complex anions [M(NO 3 ) y ] À(yÀ3) were synthesized as the composition (BDT-TTP) x [M(NO 3 ) y ]. Attempts on X-ray crystal structure analyses gave ris
## Abstract The electrochemistry of homoleptic substituted phthalocyaninato rare earth double‐decker complexes M(TBPc)~2~ and M(OOPc)~2~ [M = Y, La...Lu except Pm; H~2~TBPc = 3(4),12(13),21(22),30(31)‐tetra‐__tert__‐butylphthalocyanine, H~2~OOPc = 3,4,12,13,21,22,30,31‐octakis(octyloxy)phthalocyani