Synthetic, Structural, Spectroscopic, and Electrochemical Studies of Heteroleptic Tris(phthalocyaninato) Rare Earth Complexes
✍ Scribed by Yongzhong Bian; Lei Li; Daqi Wang; Chi-Fung Choi; Diana Y. Y. Cheng; Pehua Zhu; Renjie Li; Jianmin Dou; Rongming Wang; Na Pan; Dennis K. P. Ng; Nagao Kobayashi; Jianzhuang Jiang
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 155 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The electrochemistry of homoleptic substituted phthalocyaninato rare earth double‐decker complexes M(TBPc)~2~ and M(OOPc)~2~ [M = Y, La...Lu except Pm; H~2~TBPc = 3(4),12(13),21(22),30(31)‐tetra‐__tert__‐butylphthalocyanine, H~2~OOPc = 3,4,12,13,21,22,30,31‐octakis(octyloxy)phthalocyani
## Abstract Raman spectroscopic data in the range 500–1800 cm^−1^ for a series of 15 mixed [tetrakis(4‐chlorophenyl)porphyrinato](phthalocyaninato) double‐decker complexes with tervalent rare earths M^III^(TClPP)(Pc) (M = Y, LaLu except Ce and Pm) and intermediate‐valent cerium Ce(TClPP)(Pc) were