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Electrochemistry of 2-bromo-2-methylpropanamides. Reduction mechanism and cyclocoupling reaction with amide solvents

✍ Scribed by Maran, Flavio; Vianello, Elio; D'Angeli, Ferruccio; Cavicchioni, Giorgio; Vecchiati, Giorgio

Book ID
119945924
Publisher
Royal Society of Chemistry
Year
1987
Tongue
English
Weight
779 KB
Volume
1
Category
Article
ISSN
1472-779X

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## Abstract The reaction kinetics of 2‐bromo‐5‐nitro thiophene with piperidine was studied in a solvent with a mixture of propan‐2‐ol with methanol and __n__‐hexane at 25Β°C. The measured rate coefficients of the reaction demonstrated dramatic variations in propan‐2‐ol–__n__‐hexane mixtures and mild