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Kinetics and mechanism of the reaction of 5-bromo-2- carbonyl derivatives of furan with amines

โœ Scribed by V. N. Novikov; L. D. Babeshkina

Book ID
112325247
Publisher
Springer US
Year
1976
Tongue
English
Weight
382 KB
Volume
12
Category
Article
ISSN
0009-3122

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Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
โœ J.E. Pardue; G.R. Dobson ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo