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Mechanism of reactions of furans I: A kinetic study of the acid-catalyzed hydrolysis of furan and 2,5-dimethylfuran

✍ Scribed by E. J. Stamhuis; W. Drenth; H. van den Berg


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
328 KB
Volume
83
Category
Article
ISSN
0165-0513

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Sequential Pd(0)-catalyzed reactions for
✍ Thorsten Bach; Lars KrΓΌger πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 225 KB

4,5-Dibromofurfural (1) undergoes a regioselective Pd(0)-catalyzed C-C bond forming reaction at its C-5 position to yield the corresponding furans 3. The second bromine substituent in C-4 position can be substituted by a methyl group in a subsequent Pd(0)catalyzed cross coupling reaction. The furan