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Electrochemical transformations of alkylidenemalonates into substituted cyclopropanecarboxylates

โœ Scribed by Michail N. Elinson; Sergey K. Feducovich; Alexander A. Zakharenkov; Gennady I. Nikishin


Book ID
111730141
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
93 KB
Volume
9
Category
Article
ISSN
0959-9436

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Electrolysis of 4-substituted cyclohexanones in methanol in the presence of sodium halides in an undivided cell results in the stereoselective formation of cis-5-substituted-2,2-dimethoxycyclohexanols in 70-80% yield.