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Electrochemical transformation of alkylidenemalonates into 2-alkyl-3,3-dimethoxyalkane-1,1-dicarboxylates via rearrangement

✍ Scribed by Gennady I. Nikishin; Michail N. Elinson; Sergey K. Feducovich


Book ID
104214900
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
106 KB
Volume
32
Category
Article
ISSN
0040-4039

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## Abstract It is shown that dimethyl heptalene‐1,2‐dicarboxylates undergo rearrangements at temperatures > 200° to yield the corresponding 1,3‐dicarboxylates, which are isolated as the more stable 3,5‐dicarboxylates. ^2^H‐ and ^13^C‐labelling experiments with dimethyl 7‐isopropyl‐5,10‐dimethylhept