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Stereoselective electrochemical transformation of 4-substituted cyclohexanones into cis-5-substituted-2,2-dimethoxycyclohexanols

✍ Scribed by Michail N. Elinson; Sergey K. Feducovich; Dmitry E. Dmitriev; Alexander S. Dorofeev; Anatolii N. Vereshchagin; Gennady I. Nikishin

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
62 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Electrolysis of 4-substituted cyclohexanones in methanol in the presence of sodium halides in an undivided cell results in the stereoselective formation of cis-5-substituted-2,2-dimethoxycyclohexanols in 70-80% yield.

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