Electrochemical reduction of 4,4-dimethyl-1-phenyl-1-penten-3-one
✍ Scribed by M.A. Almirón; L. Camacho; E. Muñoz; J.L. Avila; J.V. Sinisterra
- Book ID
- 107793256
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 595 KB
- Volume
- 241
- Category
- Article
- ISSN
- 0022-0728
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Single-crystal X-ray study T = 213 K Mean '(C±C) = 0.002 A Ê R factor = 0.054 wR factor = 0.127 Data-to-parameter ratio = 18.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract 4,4‐dimethyl‐1‐(3‐4‐methylenedioxyphenyl)‐1‐pentene‐3‐ol or stiripentol was labelled by ^14^C and ^3^H. ^14^C labelling was performed on the carbone 1 of the pentene group via a four steps procedure after the carbonatation. The radiochemical yield calculated from the precursor (Ba^14^C
The NH unit on the exocyclic C C double bond in the title compound, C 25 H 23 N 3 O, interacts with the carbonyl group through an intramolecular hydrogen bond.