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Photolysis of poly(4,4-dimethyl-1-penten-3-one)

✍ Scribed by Ikuo Naito; Kenji Imamura; Hisato Shintomi; Kazuyuki Okamura; Akihiro Kinoshita


Book ID
116092582
Publisher
Elsevier Science
Year
1984
Weight
482 KB
Volume
4
Category
Article
ISSN
0144-2880

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Condensation of pyruvate and acrolein with whole cells of baker's yeast resulted in a mixture of 3-hydroxy-1-penten-4one 1 and 4-hydroxy-1-penten-3-one 2. The absolute configuration (R) and the enantiomeric excess (ee 72%) of the compound 1 were determined.