5 I, respectively. These molecules undergo further reductions. The low reduction potential of [C 6 F 5 Xe] + is in contrast to former measurements on partially fluorinated or chlorinated phenylxenonium cations. A plausible explaination for the different behaviour of these XeΒ±C compounds in electroch
Electrochemical reduction of 1,2-vinylene and 1,4-butadienylene bis-phosphonium salts
β Scribed by H.J. Cristau; B. Chabaud; L. Labaudiniere; H. Christol
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 536 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0013-4686
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In aprotic solvents such as dimethylformamide, acetonitrile or dimethylsulphoxide, the mechanism of electrochemical reduction of 1,2,4,6-substituted pyridinium cations was investigated. The stability of the key intermediate in the overall two-electron reduction, ie of the neutral radical, was increa
Syntheses o f t h e t i t l e compounds from d i e t h y l succinate and from dimethyl acetylenedicarboxylate i n 16% and 18% o v e r a l l y i e l d , respectively, are described; a procedure f o r converting these s p e c i f i c a l l y deuterated diamines i n t o the corresponding bis(ammonium n