Electrochemical Reduction of Pentafluorophenylxenonium, -diazonium, -iodonium, -bromonium, and -phosphonium Salts

✍ Scribed by S. Datsenko; N. Ignat'ev; P. Barthen; H.-J. Frohn; T. Scholten; T. Schroer; D. Welting

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: German
• Weight: 99 KB
• Volume: 624
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/(sici)1521-3749(199810)624:10<1669::aid-zaac1669>3.0.co;2-p

✦ Synopsis

5 I, respectively. These molecules undergo further reductions. The low reduction potential of [C 6 F 5 Xe] + is in contrast to former measurements on partially fluorinated or chlorinated phenylxenonium cations. A plausible explaination for the different behaviour of these Xe±C compounds in electrochemical reduction processes is given.