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Electrochemical polymerization of dicarboxylic acids—VI. Mechanism of polymerization

✍ Scribed by A. Gozlan; A. Zilkha

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
701 KB
Volume
23
Category
Article
ISSN
0014-3057

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📜 SIMILAR VOLUMES

Electrochemical polymerization of dicarb
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The electrochemical polymerization of oligomeric polyesters (prepared from adipic acid and ethylene glycol or polyethylene glycols), oligomeric polyamides (prepared from adipic or succinic acid and ethylene diamine or hexamethylene diamine), oligomeric polybutadiene (having carboxyl terminal groups)

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Al~tract--The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in various solvent systems. High melting insoluble polymers were obtained; they contained, besides the hydrocarbon chains obtained from the free radical Kolbe mechanism 2no -(nHOOC(CH:hCOOH , n "(CH:

Electrochemical polymerization of dicarb
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The electrochemical polymerizations of suberic and azelaic acids were investigated in methanol: pyridine (1:1) and the results compared with those previously obtained for adipic and sebacic acids, to find out the effect of chain length between the carboxyl groups on formation of polymer and oligomer

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✍ A. Gozlan; A. Zilkha 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 645 KB

The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the

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Akstract--The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (ct, ~o-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of t

Vinyl-Type Polymerization of Norbornene
Vinyl-Type Polymerization of Norbornene Dicarboxylic Acid Dialkyl Esters
✍ Boo-Gyo Shin; Myoung-Souk Jang; Do Yeung Yoon; Walter Heitz 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB

## Abstract **Summary:** Poly(__cis__‐norbornene‐__exo__‐2,3‐dicarboxylic acid dialkyl esters) (alkyl = Me, Et, Pr, Bu, Pen, and Hex) are synthesized as a vinyl‐type with a palladium(II) catalyst in high yield from easily prepared, pure __exo__‐monomers. The polymers show good solubility in common