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Electrochemical polymerization of 10-undecenoic acid

✍ Scribed by A. Gozlan; A. Zilkha

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
284 KB
Volume
25
Category
Article
ISSN
0014-3057

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✦ Synopsis

Akstract--The electrochemical polymerization of 10-undecenoic acid via the Kolbe reaction was studied in methanol:pyridine (1:1). Besides the expected dimeric coupling product (ct, ~o-eicosadiene), soluble oligomeric and insoluble infusible polymeric products were formed in 25% yield, by attack of the free radicals, formed from oxidation of the carboxyl groups, on the vinyl double bonds. Due to the multiple functionality of the reactants, crosslinked polymers were formed.

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