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Electrochemical polymerization of dicarboxylic acids—III. Quantitative results in the electrolysis of adipic acid

✍ Scribed by A. Gozlan; A. Zilkha

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
645 KB
Volume
23
Category
Article
ISSN
0014-3057

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✦ Synopsis

The electrochemical polymerization of adipic acid via the Kolbe synthesis was investigated in methanol, methanol-pyridine and methanol-acetonitrile mixtures. The complex variety of products formed from C4 and higher hydrocarbons, methyl esters, methyl ethers, lactones, oligomers and polymers in the various solvents were analyzed and compared. Generally the major products were the hydrocarbons and the polymers; the yield of the former decreased with increasing pyridine concentration and that of the latter increased.

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