𝔖 Bobbio Scriptorium
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Electrochemical oxidation of aldoximes

✍ Scribed by V. A. Petrosyan; M. E. Niyazymbetov; é. V. Ul'yanova

Book ID
112452516
Publisher
Springer
Year
1989
Tongue
English
Weight
297 KB
Volume
38
Category
Article
ISSN
1573-9171

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📜 SIMILAR VOLUMES

Lead tetraacetate oxidation of ketoximes
Lead tetraacetate oxidation of ketoximes and aldoximes
✍ G. Just; K. Dahl 📂 Article 📅 1966 🏛 Elsevier Science 🌐 French ⚖ 271 KB

Oxidation of aliphatic ketoximes (1) and aldoximes (2) by lead tetraacetate (Pb(OAcjq) has been reported to lead to unstable geminal nitrosoacetates and to dimeric nitrosoacetates, respectively, while a,S-unsaturated and arylaldoximes afforded oxime anhydride N-oxides and carbonyl compounds (3).

Electrochemical oxidation of acylsilanes
Electrochemical oxidation of acylsilanes
✍ Jun-ichi Yoshida; Shin-ichiro Matsunaga; Sachihiko Isoe 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 274 KB

Oxidation potentials of acylsilanes were found to be much less than those of the corresponding ketones and aldehydes. Electrochemical oxidation of acylsilanes resulted in facile cleavage of the carbon-silicon bond and introduction of oxygen and nitrogen nucleophiles at the carbonyl carbon. Therefore