A very efficient photo-sensitized oxidation of 2-(2-furyl)-1,3-dicarbonyl compounds 1 afford directly hydroperoxides 2 in stereoselective way. Compounds 2, easily isolated, can be conveniently employed in a selective epoxidation of trisubstituted allylic alcohols by a Sharpless-type procedure.
β¦ LIBER β¦
Electrochemical Oxidation of 2,3-Dimethylhydroquinone in the Presence of 1,3-Dicarbonyl Compounds
β Scribed by Hosseiny Davarani, Saied Saeed; Nematollahi, Davood; Shamsipur, Mojtaba; Najafi, Nahid Mashkouri; Masoumi, Leila; Ramyar, Somayyeh
- Book ID
- 120208575
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 132 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The reaction of 2βmethyleneβ1,3βdicarbonyl compounds **1** and nitrile oxides, which were prepared from hydroxymoyl chlorides **2** with triethylamine, gave 5,5βdisubstituted 2βisoxazolines **3** regioselectively.