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Electrochemical initiation of anionic polymerization of oligomeric acrylate esters

✍ Scribed by T.E. Lipatova; G.S. Shapoval; Ye.S. Shevchuk


Book ID
118359484
Publisher
Elsevier Science
Year
1971
Weight
569 KB
Volume
13
Category
Article
ISSN
0032-3950

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Anionic oligomerization of acrylic ester
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Abstmct--Oligomers of methyl acrylate and of ethyl acrylate were prepared by the use of methanolic and ethanolic solutions (respectively) of the corresponding sodium alkoxides as basic catalysts. Both terminally unsaturated oligomers and oligomers having alkoxyl end-groups were formed. The structure

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The anionic polymerization of caprolactam, initiated by sodium hydride with cocatalytic amounts of various esters either aromatic or aliphatic, is studied over a range of temperatures above and below the polymer melting point.