✦ LIBER ✦

Anionic polymerization of methyl acrylate

✍ Scribed by W.K Busfield; J.M Methven

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 919 KB
Volume: 14
Category: Article
ISSN: 0032-3861
DOI: 10.1016/0032-3861(73)90106-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Stereospecific anionic polymerization of

Stereospecific anionic polymerization of chiral benzyl α-[(1-phenylethoxy)methyl]acrylate

✍ Takahiro Uno; Shigeki Habaue; Yoshio Okamoto 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 1 views

Study of the propagation centre in the a

Study of the propagation centre in the anionic polymerization of acrylic monomers, 1. Spectroscopic study of methyl 2-lithioisobutyrate, an initiator for the anionic polymerization of acrylic monomers

✍ Jaroslav Kříž; Jiří Dybal; Petr Vlček; Miroslav Janata 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 824 KB

## Abstract As the simplest model for the propagation centre in the anionic polymerization of methyl methacrylate, the solution of methyl 2‐lithioisobutyrate (1) in tetrahydrofuran was studied by means of ^1^H, ^6^Li, ^7^Li and ^13^C nuclear magnetic resonance (NMR), and Raman spectroscopy at vario

Mechanism of anionic polymerization of (

Mechanism of anionic polymerization of (meth)acrylates in the presence of aluminium alkyls, 2. Kinetic investigations with methyl methacrylate in toluene

✍ Helmut Schlaad; Axel H. E. Müller 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 366 KB

## Abstract The kinetics of the polymerization of methyl methacrylate initiated by lithium alkyls (__tert__‐butyllithium or ethyl α‐lithiobutyrate) was investigated in the presence of aluminium alkyls (triethylaluminium or triisobutylaluminium) in toluene at −78°C. The rate of polymerization decrea

Polymerization of butyl acrylate in anio

Polymerization of butyl acrylate in anionic microemulsion

✍ Xiangling Xu; Bing Fei; Zhicheng Zhang; Manwei Zhang 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 364 KB 👁 3 views

Butyl acrylate was initiated with KPS or BPO to polymerize at high monomer concentration in the microemulsions with SBOA (sodium 12-butinoyloxy-9-octadecenate) as emulsifier. The microemulsion remained clear or reddish. It was found that the constant polymerization period appeared in most microemuls

Methyl nitrile ylide initiated polymeriz

Methyl nitrile ylide initiated polymerization of methyl acrylate

✍ A. K. Srivastava; P. Kumar 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 252 KB 👁 3 views

Anionic polymerization of (meth)acrylic

Anionic polymerization of (meth)acrylic monomers: anionic polymerization oftert-butyl methacrylate in toluene

✍ Zune, C; Dubois, P; Jérôme, R 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 99 KB 👁 1 views

The anionic polymerization of tBMA initiated by an organolithium compound in toluene at low temperature (À78 °C and 0 °C) has been revisited. Under these experimental conditions, no `livingness' is reported, consistently with formation of an important fraction of oligomers (M n = 650).