✦ LIBER ✦

Electrochemical behaviour of the Ni(II) ion in soda-lime-silica melts

✍ Scribed by P. Claes; J. Y. Tilquin; J. Glibert

Publisher: Wiley (John Wiley & Sons)
Year: 2010
Weight: 453 KB
Volume: 97
Category: Article
ISSN: 0037-9646
DOI: 10.1002/bscb.19880971136

No coin nor oath required. For personal study only.

✦ Synopsis

Determination of the oxidation state of solutes in glass-forming melts can be made in situ using electrochemical techniques. Nevertheless accurate voltammetric measurements are perturbed by the simultaneous influence of broader voltamperometric signals and high residual currents. The aim of this investigation was to test various voltammetric methods as well as chronopotentiometry, chronoamperometry and AC impedance plots in order to analyze the electrochemical behavior of a given solute. The Ni(ll) entity was selected, its reduction wave being well-defined. Experiments were carried out over the temperature range from 1148 to 1473 K.

📜 SIMILAR VOLUMES

Electrochemical behaviour of the Ni(II)/

Electrochemical behaviour of the Ni(II)/Ni(Hg) system in dimethylsulphoxide (DMSO) and DMSOH2O mixtures

✍ L. Janiszewska; Z. Galus 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 723 KB

Using cyclic voltammetry and single and double pulse chronocoulometry the eiectroreduction of nickel@) and oxidation of homogeneous nickel amalgam formed in situ have been studied in DMSO and its mixtures with water. Nickel(I1) electroreduction current in these media exhibitsa kineticcharacter, simi

Chemical and electrochemical behaviour o

Chemical and electrochemical behaviour of indium ions in the ZnCl22NaCl melt at 450 °C

✍ Y. Castrillejo; M.A. García; E. Barrado; P. Pasquier; G. Picard 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 677 KB

The electrochemical behaviour of the nic

The electrochemical behaviour of the nickel(II) ion at the dropping mercury electrode in the presence of some complexing agents — II

✍ P.K. Aggarwal; D.R. Crow 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 510 KB

The polarographic characteristics of the nickel(H) ion in the presence of six heterocyclic species are reported; although slight mechanistic differences exist in reduction behaviour between members of the pyridine and pyrazole series, they share the common feature that the rate-determining step invo

The electrochemical behaviour of the nic

The electrochemical behaviour of the nickel(II) ion at the dropping mercury electrode in the presence of some complexing agents—III

✍ D.R. Crow 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 519 KB

A new method is described which is applicable to the determination of overall formation constants of complexes which show irreversible reduction at the dropping mercury electrode. Values of the formation constants for the six species produced by the interaction between the NiZ+ ion and pyramle are r

Chemical and electrochemical behaviour i

Chemical and electrochemical behaviour in molten alkali hydroxides: Part II. Electrochemistry of chalcogenide ions in the molten NaOH + KOH (49 mol%) eutectic mixture

✍ P. Claes; Y. Dewilde; J. Glibert 📂 Article 📅 1988 🏛 Elsevier Science ⚖ 751 KB

Stress corrosion cracking of Inconel 600

Stress corrosion cracking of Inconel 600 in aqueous solutions at elevated temperature Part II: Effects of chloride and sulphate ions on the electrochemical behaviour of Inconel 600

✍ E. A. Ashour; F. Schneider; K. Mummert 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 German ⚖ 503 KB

## Abstract The influencing effects of temperature, potential and electrolyte composition on the electrochemical behaviour of Inconel 600 in aqueous solutions are presented. Considering these effects the connection between the data have been obtained from chemo‐mechanical fracture investigation on