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Electrochemical behaviour of nickel in nitric acid

✍ Scribed by E. Stupnišek-Lisac; M. Karšulin


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
367 KB
Volume
29
Category
Article
ISSN
0013-4686

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✦ Synopsis


Theelectrochemical investigationsofnickelin a wide range ofconcentrations (l-14.6 M)ofnitric acid were studied by potentiostatic, potentiodynamic and coulostatic method and by weight-loss measurements. The potentiostatic current-potential curves of nickel in nitric acid solutions can be classified into three categories, according to the proportion of the concentration of the acid. An increase of nitric acid concentration increases the influence of the cathodic reactions in the systems. The Importance of cathodic reactions has been investigated by eliminating HNOl by addition of p-nitro aniline in the electrolyte. The coulostatic polarization has given distinct repassivation curves, indicating an intermediate state of nickel electrode between activeand passive state. In the first part of repassivating process the potential value is more positive than the stationary potential of spontaneous passivation of nickel electrode in concentrated nitric acid. The return to the stationary potential of the passivity is a slow, time-dependant process. According to the experimental results and data given in the literature, it may be possible that in the beginning of the passivation process on nickel Ni(NO,), x 4 Hz0 forms which changes to NiOz and than transforms slowly 10 NiO.


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