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Electrocatalytic oxidation of propargyl alcohol at platinum electrodes in acid medium: A kinetic study

✍ Scribed by L. Roquet; E.M. Belgsir; J.-M. Léger; C. Lamy

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
617 KB
Volume
41
Category
Article
ISSN
0013-4686

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✦ Synopsis

This paper deals with the electrocatalytic oxidation of propargyl alcohol (PA) at a platinum electrode in aqueous acid medium. During prolonged electrolyzes, the transformation is found to be highly selective towards the production of propargyl aldehyde (PAL). The effects on the selectivity of kinetic parameters, as the initial concentration of propargyl alcohol and the current density, are evaluated and correlated to the rate constant.

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