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Electrocatalytic dehalogenation of α-bromoketones in the presence of Cp2TiCl2

✍ Scribed by O. M. Nikitin; G. V. Gavrilova; T. V. Magdesieva

Publisher
Springer
Year
2007
Tongue
English
Weight
457 KB
Volume
56
Category
Article
ISSN
1573-9171

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Cp2TiCl-mediated selective reduction of
Cp2TiCl-mediated selective reduction of α,β-unsaturated ketones
✍ Lionel Moisan; Christophe Hardouin; Bernard Rousseau; Eric Doris 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 56 KB

A mild method for the selective reduction of a,b-unsaturated ketones is reported. The process described herein involves, as the active species, the low-valent titanium complex Cp 2 TiCl.