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Electroabsorption Studies of Metal-to-Ligand Charge Transfer in Ru(phenanthroline) 32+ : Evidence for Intrinsic Charge Localization in the Initially Formed Excited State

✍ Scribed by Karki, Laba; Hupp, Joseph T.


Book ID
126183923
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
119 KB
Volume
36
Category
Article
ISSN
0020-1669

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Picosecond resonance Raman has been employed in a two-color pump/probe experiment to re-evaluate the assignments of metal to ligand charge transfer ground and excited state bands in tris-2,2'-bipyridine Ru(II). It is shown that there is no spectral overlap between ground and excited state bands and