Ultrafast Dynamics in the Metal-to-Ligand Charge Transfer Excited-State Evolution of [Ru(4,4‘-diphenyl-2,2‘-bipyridine) 3 ] 2+
✍ Scribed by Damrauer, Niels H.; McCusker, James K.
- Book ID
- 126053987
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 186 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures
Picosecond resonance Raman has been employed in a two-color pump/probe experiment to re-evaluate the assignments of metal to ligand charge transfer ground and excited state bands in tris-2,2'-bipyridine Ru(II). It is shown that there is no spectral overlap between ground and excited state bands and