Photooxidation of (2,2'-bipyridine)(3,4-toluenedithiolato)platinum(II) following ligand-to-ligand and charge-transfer excitation
โ Scribed by Vogler, Arnd; Kunkely, Horst
- Book ID
- 127189158
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 267 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The electronic structure and the optical ligand-to-ligand charge transfer (LLCT) of the pseudotetrahedral complex Zn(2,2'bipyridyl) (3,4-tolueneditbiolate) is interpreted on the basis of EHT calculations. By comparison with square-planar complexes, it is shown that the extent of electron delocalizat
## Abstract The __transโcis__ isomerization of the styrylpyridine carbonโcarbon double bond induced by visible light irradiation in __fac__โ[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2โฒโbipyridine; stpy = __t__โ4โstyrylpyridine) has been investigated by means of quantumโchemical methods. The structures