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Electro-optical properties of the first rhenium-hydrazone complex, fac-Re(CO)3(dpknph)*Cl

โœ Scribed by Mohammed Bakir; Kamaluddin Abdur-Rashid

Book ID
110246065
Publisher
Springer
Year
1999
Tongue
English
Weight
118 KB
Volume
24
Category
Article
ISSN
0340-4285

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๐Ÿ“œ SIMILAR VOLUMES

Rhenium tricarbonyl chloro of di-2-pyrid
Rhenium tricarbonyl chloro of di-2-pyridylketone 4-aminobenzoyl hydrazone (dpk4abh), fac-[Re(CO)3(ฮบ2-N,N-dpk4abh)Cl]: Synthesis, spectroscopic and electrochemical properties
โœ Mohammed Bakir; Orville Green ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 709 KB

The reaction between di-2-pyridyl ketone 4-aminobenzoylhydrazone hydrate (dpk4abh.H 2 O) and [Re(CO) 5 Cl] in refluxing toluene gave fac-[Re(CO) 3 (j 2 -N,N-dpk4abh)Cl]. Hydrolysis of fac-[Re(CO) 3 (j 2 -N,N-dpk4abh)Cl] to form fac-[Re(CO) 3 (j 3 -N,O,N-dpkO,OH)] occurs in wet solvents. The identity