Electric-field effects on the [FeFe]-hydrogenase active site
β Scribed by Finkelmann, Arndt R.; Stiebritz, Martin T.; Reiher, Markus
- Book ID
- 120577773
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 590 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1359-7345
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π SIMILAR VOLUMES
## Abstract A short overview of diiron dichalcogenolato (Se and Te) model complexes related to the chemistry of the diiron subsite of [FeFe] hydrogenase is presented. These model complexes allow direct comparison with the diiron dithiolato compound analogues for their ability to catalyze the format
## Abstract The oxidation of the hexacarbonyl(1,3βdithiolatoβ__S__,__S__β²)diiron complexes **4a**β**4c** with varying amounts of dimethyldioxirane (DMD) was systematically studied. The chemoselectivity of the oxidation products depended upon the substituent R (R=H, Me, 1/2 (CH~2~)~5~). For R=H, fou